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1.56 acres of commercially zoned land. Favourable Hotel Feasibility Study Completed. Brockville is conveniently located on Highway 401. This major thoroughfare provides direct access to Montreal, Quebec City, and Maritime Canada, as well as westerly access to Toronto, Windsor and Detroit. Found in the County of Leeds and situated in the middle of the St. Lawrence | Great Lakes area on the world's largest inland waterway, Brockville offers business and industry accessibility to the major commercial international markets.